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Beilstein J. Org. Chem. 2014, 10, 1942–1950, doi:10.3762/bjoc.10.202
Graphical Abstract
Scheme 1: Grignard reaction of aldehyde 3 and oxidation of the resulting mixture of alcohols 4–7. Reagents an...
Figure 1: Molecular structure (DIAMOND drawing with adjacent ChemDraw image) of o-tolyl derivative 8. Atomic ...
Figure 2: Molecular structure (DIAMOND drawing with adjacent ChemDraw image) of benzyl derivative 9. Atomic d...
Scheme 2: Proposed mechanism for Grignard reaction leading to benzyl→o-tolyl rearrangement (path 1). R = sacc...
Scheme 3: Proposed mechanism [24,25] for Grignard reaction leading to 1-naphthylmagnesiumchloride→1-methylnaphthalen...